Concepedia

η2-Alkyne Binding

η²-Alkyne Binding is a coordination mode in which an alkyne ligand functions as a two-electron donor to a metal center through side-on coordination involving the π-bonding electrons of its carbon–carbon triple bond, thereby forming a metallacyclopropane-like interaction.

44

Publications

1.5K

Citations

185

Authors

54

Institutions

Publications per year

2017–2026

3

Variants

η2-Alkyne Coordination

Parents

Publications

44

Gold η<sup>2</sup>-Coordination to Unsaturated and Aromatic Hydrocarbons: The Key Step in Gold-Catalyzed Organic Transformations

Hubert Schmidbaur, Annette Schier · Organometallics · 2009 · 275 citations

, , +16

Monomeric Bis(η<sup>2</sup>-alkyne) Complexes of Copper(I) and Silver(I) with η<sup>1</sup>-Bonded Alkyl, Vinyl, and Aryl Ligands

Maurits D. Janssen, Katrin Köhler, Mathias Herres et al. · Journal of the American Chemical Society · 1996 · 99 citations

, , +16

Insertion of norbornadiene into the aryl–palladium bond; synthesis, structure and dynamics of intramolecular η<sup>2</sup>-arene palladium species

Chen-Shun Li, Chien‐Hong Cheng, Fen‐Ling Liao et al. · Journal of the Chemical Society Chemical Communications · 1991 · 80 citations

, , +12

Reactivity of Indenyl−Ruthenium(II) Vinylidene Complexes:  Selective Synthesis of Alkenyl−Phosphonio Derivatives via Nucleophilic Addition of Triphenylphosphine on Their η<sup>2</sup>-Alkyne Tautomers. Theoretical Study of the η<sup>1</sup>-Vinylidene−η<sup>2</sup>-Alkyne Tautomerization

Victorio Cadierno, M. Pilar Gamasa, José Gimeno et al. · Organometallics · 2001 · 66 citations

, , +17

DFT Study of Internal Alkyne-to-Disubstituted Vinylidene Isomerization in [CpRu(PhC≡CAr)(dppe)]<sup>+</sup>

Miho Otsuka, Noriko Tsuchida, Yousuke Ikeda et al. · Journal of the American Chemical Society · 2012 · 59 citations

, , +15

1–5 of 44

Authors

185

  1. MB
    Michael B. Hursthouse

    University of Southampton, United Kingdom

    3 publications · 87 citations

    3

    h-index

  2. VB
    V.V. Burlakov

    University of Rostock, Germany

    2 publications · 61 citations

    2

    h-index

  3. AL
    Anthony L. Spek

    Utrecht University, Netherlands

    2 publications · 142 citations

    2

    h-index

  4. WB
    Wolfgang Baumann

    Leibniz Institute for Catalysis, Germany

    2 publications · 61 citations

    2

    h-index

  5. JF
    John F. Nixon

    University of Sussex, United Kingdom

    2 publications · 40 citations

    2

    h-index

1–5 of 185

Institutions

54

  1. A. N. Nesmeyanov Institute of Organoelement Compounds

    Moscow, Russia

    3 h-index

    12 publications

    312 citations

  2. Technical University of Munich

    Munich, Germany

    2 h-index

    4 publications

    606 citations

  3. University of Oxford

    Oxford, United Kingdom

    2 h-index

    6 publications

    125 citations

  4. University of Sussex

    Brighton, United Kingdom

    2 h-index

    7 publications

    202 citations

  5. Laboratoire de Chimie de Coordination

    Toulouse, France

    2 h-index

    12 publications

    313 citations

  6. Centre National de la Recherche Scientifique

    Paris, France

    2 h-index

    12 publications

    313 citations

  7. University of California, Berkeley

    Berkeley, United States

    1 h-index

    4 publications

    60 citations

  8. University of Rostock

    Rostock, Germany

    1 h-index

    3 publications

    69 citations

1–8 of 54

Venues

  1. Journal of Organometallic Chemistry

    8 publications · 161 citations

    8

    h-index

  2. Organometallics

    6 publications · 464 citations

    6

    h-index

  3. Journal of the American Chemical Society

    JACS · 3 publications · 179 citations

    3

    h-index

  4. Chemical Communications

    ChemComm · 3 publications · 109 citations

    3

    h-index

  5. Polyhedron

    3 publications · 67 citations

    3

    h-index

1–5