Skeletal electron counting in cluster species. Some generalisations and predictions

Kenneth Wade

Inorganic and Nuclear Chemistry Letters

BiologyCluster ScienceElectron SpectroscopyNatural SciencesEvolutionary Biology +3

C-arylation and C-heteroarylation of icosahedral carboranes via their copper(I) derivatives

Robert Coult, Mark A. Fox, Wendy R. Gill, +3

Journal of Organometallic Chemistry

Chemical EngineeringCross-coupling ReactionEngineeringHeterocyclicIcosahedral Carboranes +4

Exo-π-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C₂B₁₀H₁₀ (X = F, OH or NH₂) and related anions

L.A. Boyd, W. Clegg, Royston C. B. Copley, +7

Dalton Transactions

Natural SciencesChemical BondPhenyl-ortho-carborane BearingCovalent Bonded FrameworkSecond Cage Hypercarbon +10

Definitive crystal structures of ortho-, meta- and para-carboranes: supramolecular structures directed solely by C–H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

Matthew G. Davidson, T.G. Hibbert, Judith A. K. Howard, +2

Chemical Communications

Supramolecular AssemblyEngineeringDefinitive Crystal StructuresUnsubstituted CarboranesStructure Elucidation +11

Deboronation of C-substituted ortho- and meta-closo-carboranes using “wet” fluoride ion solutions

Mark A. Fox, Wendy R. Gill, Penelope L. Herbertson, +3

Polyhedron

Inorganic ChemistryChemical EngineeringEngineeringFluorous SynthesisOrganic Chemistry +2

Adducts of cyclopenyldienylsodium and methylcyclopentadienylsodium with oxygen bases and nitrogen bases: Structure of cyclopentadienylsodiumtetramethylethylenediamine, Na(C5H5)(Me2NCH2CH2NMe2)

Takanobu Aoyagi, H. M. M. Shearer, Kenneth Wade, +1

Journal of Organometallic Chemistry

Nitrogen BasesHeterocyclicBiochemistryNatural SciencesStructure Elucidation +5

Intra- and inter-molecular carboranyl C–H⋯N hydrogen bonds in pyridyl-containing ortho-carboranesElectronic supplementary information (ESI) available: rotatable 3-D molecular structure diagrams of experimental structures of 1–4 and of MP2/6-31G* optimised geometries 1a–7b in CHIME format. Computed GIAO NMR data for 1b–4c. See http://www.rsc.org/suppdata/dt/b2/b209931d/

E.S. Alekseyeva, Andrei S. Batsanov, L.A. Boyd, +6

Dalton Transactions

EngineeringChime FormatOrganic ChemistryChemistryHeterocycle Chemistry +14

Polymers and ceramics based on icosahedral carboranes. Model studies of the formation and hydrolytic stability of aryl ether, ketone, amide and borane linkages between carborane units

David A. Brown, Howard M. Colquhoun, J. Anthony Daniels, +3

Journal of Materials Chemistry

Materials ScienceOrganic Material ChemistryChemical EngineeringNovel OrganocatalystsFree Carboranes +12

Transmission of electronic effects by icosahedral carboranes; skeletal carbon-13 chemical shifts and ultraviolet–visible spectra of substituted aryl-p-carboranes (1,12-dicarba-closo-dodecaboranes)

Mark A. Fox, J. A. H. MACBRIDE, R.J. Peace, +1

Journal of the Chemical Society Dalton Transactions

Carbon-13 Nmr ShiftsDerivative (Chemistry)Organic Material ChemistryDerivativesHeterocyclic +12

The laddering principle in lithium amide chemistry: the crystal and molecular structure of the pyrrolididolithium adduct [H₂C(CH₂)₃NLi]₃·MeN(CH₂CH₂NMe₂)₂

David R. Armstrong, Donald Barr, W. Clegg, +4

Journal of the Chemical Society Chemical Communications

Materials ScienceInorganic ChemistryCrystal StructureEngineeringStructure Elucidation +11