Darryl P. Klein

Synthesis and reactivity of (pentamethylcyclopentadienyl)iridium bis(thiolate) and thiolate hydride complexes

Darryl P. Klein, Grant M. Kloster, Robert G. Bergman · Journal of the American Chemical Society · 1990 · 77 citations

Inorganic Chemistry, Molecular Sciences, Engineering +15

Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates

Darryl P. Klein, Jeffrey C. Hayes, Robert G. Bergman · Journal of the American Chemical Society · 1988 · 65 citations

Engineering, Heterocyclic, Biochemistry +12

Synthesis and reactivity of (.eta.5-C5Me5)(PMe3)Ir(CH2): a monomeric (pentamethylcyclopentadienyl)iridium methylene complex

Darryl P. Klein, Robert G. Bergman · Journal of the American Chemical Society · 1989 · 47 citations

Inorganic Chemistry, Molecular Sciences, Engineering +15

Activation of organic carbonyl compounds by Lewis acids: relative reactivities of .sigma. and .pi. adducts toward nucleophiles and implications for enantioselective addition reactions

Darryl P. Klein, John A. Gladysz · Journal of the American Chemical Society · 1992 · 32 citations

Engineering, Biochemistry, Natural Sciences +11

π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(OCRR′)]+X−; a marked electronic effect upon the binding mode

Darryl P. Klein, D.M. Dalton, N. Quirós Méndez et al. · Journal of Organometallic Chemistry · 1991 · 28 citations