Heterogeneous interfacial engineering has garnered widespread attention for optimizing polarization loss and enhancing the performance of electromagnetic wave absorption. A novel Kirkendall effect-assisted electrostatic self-assembly method is employed to construct a metal-organic framework (MOF, MIL-88A) decorated with Ni-Fe layered double hydroxide (LDH), forming a multilayer nano-cage coated with Ti₃C₂T_x. By modulating the surface adsorption of Ti₃C₂T_x on LDH, the heterointerfaces in MOF-LDH-MXene ternary composites exhibit excellent interfacial polarization loss. Additionally, the Ni-Fe LDH@Ti₃C₂T_x nano-cage exhibits a large specific surface area, abundant defects, and a large number of heterojunction structures, resulting in excellent electromagnetic wave absorption performance. The MIL-88A@Ni-Fe LDH@Ti₃C₂T_x-1.0 nano-cage achieves a reflection loss value of -46.7 dB at a thickness of 1.4 mm and an effective absorption bandwidth of 5.12 GHz at a thickness of 1.8 mm. The heterojunction interface composed of Ni-Fe LDH and Ti₃C₂T_x helps to enhance polarization loss. Additionally, Ti₃C₂T_x forms a conductive network on the surface, while the cavity between the MIL-88A core and the Ni-Fe LDH shell facilitates multiple attenuations by increasing the transmission path of internal incident waves. This work may reveal a new structural design of multi-component composites by heterointerfaces engineering for electromagnetic wave absorption.

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1	Engineering	4	4	331
2	Materials Science	4	4	331
3	Applied Physics	3	3	301
4	Chemical Engineering	1	1	30
5	Hybrid Materials	1	1	111

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