Aqueous rechargeable zinc-ion batteries (ARZIBs) are considered as an emerging energy storage technology owing to their low cost, inherent safety, and reasonable energy density. However, significant challenges associated with electrodes, and aqueous electrolytes restrict their rapid development. Herein, ethylene glycol-choline chloride (Eg-ChCl) based hydrated deep-eutectic electrolytes (HDEEs) are proposed for RZIBs. Also, a novel V₁₀O₂₄·nH₂O@rGO composite is prepared and investigated in combination with HDEEs. The formulated HDEEs, particularly the composition of 1 ml of EG, 0.5 g of ChCl, 4 ml of H₂O, and 2 M ZnTFS (1-0.5-4-2 HDEE), not only exhibit the lowest viscosity, highest Zn²⁺ conductivity (20.38 mS cm^-1), and the highest zinc (Zn) transference number (t₊ = 0.937), but also provide a wide electrochemical stability window (>3.2 V vs ZnǁZn²⁺) and enabledendrite-free Zn stripping/plating cycling over 1000 hours. The resulting ZnǁV₁₀O₂₄·nH₂O@rGO cell with 1-0.5-4-2 HDEE manifests high reversible capacity of ≈365 mAh g^-1 at 0.1 A g^-1, high rate-performance (delivered ≈365/223 mAh g^-1 at 0.1/10 mA g^-1) and enhanced cycling performance (≈63.10% capacity retention in the 4000^th cycle at 10 A g^-1). Furthermore, 1-0.5-4-2 HDEE support feasible Zn-ion storage performance across a wide temperature range (0-80 °C) FInally, a ZnǁV₁₀O₂₄·nH₂O@rGO pouch-cell prototype fabricated with 1-0.5-4-2 HDEE demonstrates good flexibility, safety, and durability.

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