21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T4fb,Rechargeable aqueous Zn-ion batteries have been deemed a promising energy storage device. However, the dendrite growth and side reactions have hindered their practical application. Herein, inspired by the ultrafluidic and K⁺ ion-sieving flux through enzyme-gated potassium channels (KcsA) in biological plasma membranes, a metal-organic-framework (MOF-5) grafted with -ClO₄ groups (MOF-ClO₄) as functional enzymes is fabricated to mimic the ultrafluidic lipid-bilayer structure for gating Zn²⁺ 'on' and anions 'off' states. The MOF-ClO₄ achieved perfect Zn²⁺/SO₄ ^2- selectivity (∼10), enhanced Zn²⁺ transfer number ([Formula: see text]) and the ultrafluidic Zn²⁺ flux (1.9 × 10^-3 vs. 1.67 mmol m^-2 s^-1 for KcsA). The symmetric cells based on MOF-ClO₄ achieve a lifespan of over 5400 h at 10 mA cm^-2/20 mAh cm^-2. Specifically, the performance of the PMCl-Zn//V₂O₅ pouch cell keeps 81% capacity after 2000 cycles at 1 A g^-1. The regulated ion transport, by learning from a biological plasma membrane, opens a new avenue towards ultralong lifespan aqueous batteries.23:T4dc,Hierarchical self-assembly with long-range order above centimeters widely exists in nature. Mimicking similar structures to promote reaction kinetics of electrochemical energy devices is of immense interest, yet remains challenging. Here, we report a bottom-up self-assembly approach to constructing ordered mesoporous nanofibers with a structure resembling vascular bundles via electrospinning. The synthesis involves self-assembling polystyrene (PS) homopolymer, amphiphilic diblock copolymer, and precursors into supramolecular micelles. Elongational dynamics of viscoelastic micelle solution together with fast solvent evaporation during electrospinning cause simultaneous close packing and uniaxial stretching of micelles, consequently producing polymer nanofibers consisting of oriented micelles. The method is versatile for the fabrication of large-scale ordered mesoporous nanofibers with adjustable pore diameter and various compositions such as carbon, SiO₂, TiO₂ and WO₃. The aligned longitudinal mesopores connected side-by-side by tiny pores offer highly exposed active sites and expedite electron/ion transport. The assembled electrodes deliver outstanding performance for lithium metal batteries.

#	Concept	H-Index	Publications	Citations
1	Engineering	1	1	59
2	Electrical Engineering	1	1	59
3	Charge Transport	1	1	59
4	Electrical Insulation	1	1	59
5	Surface Science	1	1	59

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