21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T528,Heterobimetallic Ln(III)-Pd(0) complexes (Ln = Y, Sm, Gd, Yb) featuring tetranuclear structures with COD as bridges were obtained via the metallation of tris(phosphinoamido) rare-earth metal complexes [Ph₂PNAd]₃Ln (Ad = adamantyl) with (COD)Pd(CH₂SiMe₃)₂. Notably, the Sc(III)-Pd(0) complex possesses a C₃-symmetry with a very short Sc-Pd bond length of 2.432(2) Å, while the tetranuclear complexes exhibited versatile structures both in solution and in the solid state. Reduction of the trivalent complex (Ph₂PNAd)₃Yb with one equivalent of KC₈ in the presence of 18-c-6 afforded the divalent complex [(Ph₂PNAd)₃Yb][(18-c-6)K(THF)₂], which was further reacted with (Ph₃P)₄Pd to form the first Yb(II)-Pd(0) complex. The Pd(0) → Yb dative interaction weakened significantly from Yb(III) to Yb(II) based on computational studies, which was attributed to the attenuated Lewis acidity of the Yb(II) center. Reactions of Ln(III)-Pd(0) complexes (Ln = Sc and Yb) with the disulfide PhSSPh showed that the Pd(0) center served as a two-electron donor while the reaction apparently occurred on the Ln(III) centers to form Ln(III)-Pd(0) bis-sulfide complexes.

#	Concept	H-Index	Publications	Citations
1	Engineering	1	1	54
2	Chemical Engineering	1	1	54
3	Chemistry	1	1	54
4	Catalysis	1	1	54
5	Thermal Hydraulics	1	1	54

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