Xiao Liang Luo

Homogeneous catalysis of silane alcoholysis via nucleophilic attack by the alcohol on an Ir(.eta.2-HSiR3) intermediate catalyzed by [IrH2S2(PPh3)2]SbF6 (S = solvent)

Xiao Liang Luo, Robert H. Crabtree · Journal of the American Chemical Society · 1989 · 228 citations

Chemical Engineering, Nucleophilic Attack, Engineering +11

Solution equilibrium between classical and nonclassical polyhydride tautomers [ReH4(CO)L3]+ and [ReH2(.eta.2-H2)(CO)L3]+ (L = PMe2Ph). Equilibrium isotope effects and an intermediate trihydrogen complex in intramolecular site exchange of dihydrogen and hydride ligands

Xiao Liang Luo, Robert H. Crabtree · Journal of the American Chemical Society · 1990 · 83 citations

Inorganic Chemistry, Engineering, Biochemistry +13

Reaction of heptahydridobis(triphenylphosphine)rhenium with silanes: preparation and characterization of the first silyl polyhydride complexes, ReH6(SiR3)(PPh3)2 (SiR3 = SiPh3, SiEt3, SiHEt2)

Xiao Liang Luo, Denise Baudry, P. Boydell et al. · Inorganic Chemistry · 1990 · 46 citations

Inorganic Chemistry, Chemical Engineering, Engineering +10

Synthesis and structural studies of some new rhenium phosphine heptahydride complexes. Evidence for classical structures in solution

Xiao Liang Luo, Robert H. Crabtree · Journal of the American Chemical Society · 1990 · 43 citations

Inorganic Chemistry, Engineering, Biochemistry +15

The first polyhydrides stabilized only by N-donor ligands, hexahydro[hydrotris(pyrazolyl)borato]rhenium and heptahydro[dipyrazolylmethane]rhenium

Douglas G. Hamilton, Xiao Liang Luo, Robert H. Crabtree · Inorganic Chemistry · 1989 · 36 citations

Inorganic Chemistry, Molecular Sciences, Engineering +13