C.A. Smith

Tetranuclear carbidotungsten and nitridomolybdenum clusters supported by alkoxide ligands: W4(C)(OCHMe2)12(NMe) and Mo4(N)2(OCHMe2)12

Malcolm H. Chisholm, Kirsten Folting, John C. Huffman et al. · Journal of the American Chemical Society · 1985 · 36 citations

Materials Science, Inorganic Chemistry, Engineering +12

Metal alkoxides-models for metal oxides. 9. Hydridoditungsten alkoxides: W2(H)(O-iso-Pr)8Na.cntdot.diglyme and W2(H)(I)(OCH2-tert-Bu)6(H2NMe). Further investigations of the reaction between W2(NMe2)6(M.tplbond.M) and iso-PrOH leading to W4(H)2(O-iso-Pr)14

Malcolm H. Chisholm, John C. Huffman, C.A. Smith · Journal of the American Chemical Society · 1986 · 28 citations

Materials Science, Inorganic Chemistry, Metal Alkoxides-models +12

Example of mechanistic similarity between oxidative addition and classical donor coordination

J. F. Harrod, C.A. Smith, K. A. Than · Journal of the American Chemical Society · 1972 · 24 citations

Classical Donor Coordinationj, Engineering, Chemical Analysis +18

Preparation and characterization of hexacyclohexoxido- and trispinacolato-ditungsten (MM). A comparison of staggered and eclipsed ethane-like O3WWO3 units

Malcolm H. Chisholm, Kirsten Folting, Mark J. Hampden‐Smith et al. · Polyhedron · 1987 · 23 citations

Metal alkoxides - Models for metal oxides. 12. The first molecular carbido cluster of tungsten, W4(C)(NMe)(OCHMe2)12 and carbon-13 NMR spectroscopic evidence for a related oxo-carbido cluster, W4(C)(O)(OCHMe2)12, formed in the stepwise reductive cleavage of carbon monoxide by lower valent tungsten alkoxides

Malcolm H. Chisholm, David L. Clark, John C. Huffman et al. · Organometallics · 1987 · 17 citations

Materials Science, Inorganic Chemistry, Stepwise Reductive Cleavage +13