21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T531,Pure and Eu³⁺-doped zinc sulfide (ZnS) crystallites were synthesized through a hydrothermal method using water and ethanol (W/E) as the solvent. The powder samples have been characterized systematically using a number of characterization techniques such as X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, photoluminescence spectroscopy, and UV-vis absorption spectroscopy. The band gap of ZnS and ZnS/xEu³⁺ was calculated according to absorption spectroscopy, and an obvious red shift with the increasing molar fraction of Eu³⁺-doped ions was found. The luminescent mechanism of ZnS was explored by measuring the emission spectra of ZnS with different ratios of Zn and S. The emission spectra of ZnS/xEu³⁺ included the characteristic emission peak of ZnS and Eu³⁺ ions. The CIE chromaticity coordinates of the ZnS/xEu³⁺ sample varied with the molar fraction of Eu³⁺ ions. The emission intensity and morphology changed with the ratio of W/E in the process of hydrothermal reaction. The results indicate that the luminescence of the ZnS crystallite can be modulated by doping a certain amount of Eu³⁺ ions, changing the ratio of Zn and S, or adding moderate ethanol as the reaction medium.

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