23:T4f4,Organic cathode materials (OCMs) for rechargeable Li and Na batteries show great advantages in resource sustainability and huge potential in electrochemical performance but suffer from dissolution problems and costly synthesis. Herein, for the first time, we investigated the copolymer of benzoquinone (BQ) and pyrrole (Py), namely, poly(benzoquinone-pyrrole) (PBQPy), as an OCM for Li batteries. The low-cost raw materials and solvent-free synthesis provide PBQPy much brighter prospects in large-scale production compared to other carbonyl-based polymer cathode materials. Nevertheless, PBQPy showed one of the best electrochemical performances among all OCMs, including excellent energy density (2.32 V × 255 mAh g^-1 = 592 Wh kg^-1), rate capability (79%@2000 mA g^-1), and cycling stability (81%@1000th cycle). By introducing poly(benzoquinone-methyl pyrrole) for comparison, as well as employing density functional theory calculations and various characterizations for in-depth understanding, the synthesis mechanism, polymer structure, electrochemical behavior, and redox mechanism were clearly clarified. It is believed that this work will encourage more efforts to develop cost-effective OCMs toward practical organic batteries.24:T480,The radial distribution of the end-to-end distance R_ee is crucial for quantifying the global size and flexibility of a linear polymer. For semiflexible polymers, several analytical formulas have been derived for the radial distribution of R_ee ignoring the stretching flexibility. However, for semiflexible oligomers, such as DNA or RNA, the stretching flexibility can be rather pronounced and can significantly affect the radial distribution of R_ee. In this study, we obtained an extended formula that includes the stretch modulus to describe the distribution of R_ee for semiflexible oligomers on the basis of previous formulas for semiflexible polymers without stretching flexibility. The extended formula was validated by extensive Monte Carlo simulations over wide ranges of the stretch modulus and persistence length, as well as all-atom molecular dynamics simulations of short DNAs and RNAs. Additionally, our analyses showed that the effect of stretching flexibility on the distribution of R_ee becomes negligible for DNAs longer than ∼130 base pairs and RNAs longer than ∼240 base pairs.

#	Concept	H-Index	Publications	Citations
1	Medicine	2	2	124
2	Natural Sciences	2	2	124
3	Molecular Biology	2	2	124
4	Biochemistry	1	1	47
5	Structural Biology	1	1	47

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