Photoexcitation of flavoenzymes enables a stereoselective radical cyclization

Kyle F. Biegasiewicz, Simon J. Cooper, Xin Gao, +7

Science

Catalytic promiscuity enabled by photoredox catalysis in nicotinamide-dependent oxidoreductases

Kyle F. Biegasiewicz, Simon J. Cooper, Megan A. Emmanuel, +2

Nature Chemistry

Photoredox CatalysisEngineeringPhotoredox ProcessBiochemistryPhotochemistry +4

Asymmetric redox-neutral radical cyclization catalysed by flavin-dependent ‘ene’-reductases

Michael J. Black, Kyle F. Biegasiewicz, Andrew J. Meichan, +4

Nature Chemistry

BiochemistryRadical (Chemistry)Organic ChemistryRedox ChemistryRedox Biology

Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins

Claire G. Page, Simon J. Cooper, Jacob S. DeHovitz, +10

Journal of the American Chemical Society

Photoenzymatic Catalysis Enables Radical‐Mediated Ketone Reduction in Ene‐Reductases

Braddock A. Sandoval, Sarah I. Kurtoic, Megan Chung, +2

Angewandte Chemie International Edition

Photoredox CatalysisCross-coupling ReactionEngineeringPhotoredox ProcessPhotochemistry +13

Photoenzymatic Hydrogenation of Heteroaromatic Olefins Using ‘Ene’‐Reductases with Photoredox Catalysts

Yuji Nakano, Michael J. Black, Andrew J. Meichan, +5

Angewandte Chemie International Edition

Enzyme Active SiteVinyl PyridineVisible LightEngineeringPhotochemistry +12

Organocatalytic Enantioselective α-Hydroxymethylation of Aldehydes: Mechanistic Aspects and Optimization

Robert K. Boeckman, Kyle F. Biegasiewicz, Douglas J. Tusch, +1

The Journal of Organic Chemistry

Novel OrganocatalystsEngineeringα-Hydroxymethylation Processα-Diarylprolinol TrimethylsilylIntermediate Lactol +8

Development of a general approach to the synthesis of a library of isoflavonoid derivatives

Kyle F. Biegasiewicz, James S. Gordon, Deana A. Rodriguez, +1

Tetrahedron Letters

Medicinal ChemistryIsoflavonoid DerivativesBioorganic ChemistryDerivative (Chemistry)Biochemistry +7

Photoenzymatic Catalysis Enables Radical‐Mediated Ketone Reduction in Ene‐Reductases

Braddock A. Sandoval, Sarah I. Kurtoic, Megan Chung, +2

Angewandte Chemie

Enzyme Active SitePhotoredox CatalysisEngineeringPhotoredox ProcessBiochemistry +12

Decarboxylative Bromooxidation of Indoles by a Vanadium Haloperoxidase

Clare E. Wells, Lauren P.T. Ramos, Lauren J. Harstad, +4

ACS Catalysis

Novel OrganocatalystsBiosynthesisBioorganic ChemistryEngineeringBiochemistry +13