Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

P. Spies, Gerhard Erker, Gerald Kehr, +4

Chemical Communications

EngineeringHeterocyclicBiochemistryNatural SciencesMolecular Biology +3

IBiox[(−)-menthyl]: A Sterically Demanding Chiral NHC Ligand

Sebastian Würtz, Claudia Lohre, Roland Fröhlich, +2

Journal of the American Chemical Society

Identification of a new class of biopolymer: bacterial synthesis of a sulfur-containing polymer with thioester linkages

Tina Lütke‐Eversloh, Alexander Steinbüchel, Heinrich Luftmann, +1

Microbiology

BiosynthesisThioester LinkagesEngineeringNatural PolymerBiocatalysis +13

Functional‐Group Tolerance in Frustrated Lewis Pairs: Hydrogenation of Nitroolefins and Acrylates

Lutz Greb, Constantin G. Daniliuc, Klaus Bergander, +1

Angewandte Chemie International Edition

Materials ScienceEngineeringBiochemistryFunctional‐group ToleranceDecreased Lewis Acidity +9

Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach

Felix Strieth‐Kalthoff, Christian Henkel, Michael Teders, +10

Chem

EngineeringCombined Screening ApproachChemical TransformationEnergy EfficiencyEnergy Conversion +4

Reversible Carbon Dioxide Binding by Simple Lewis Base Adducts with Electron-Rich Phosphines

Florenz Buß, Paul Mehlmann, Christian Mück‐Lichtenfeld, +2

Journal of the American Chemical Society

Inorganic ChemistryChemical EngineeringElectron-rich PhosphinesCarbon DioxideEngineering +9

The formation of all-cis-(multi)fluorinated piperidines by a dearomatization–hydrogenation process

Zackaria Nairoukh, Marco Wollenburg, Christoph Schlepphorst, +2

Nature Chemistry

Chemical EngineeringEngineeringDearomatization–hydrogenation ProcessFluorous SynthesisOrganic Chemistry +2

Metal-free dihydrogen activation chemistry: structural and dynamic features of intramolecular P/B pairs

P. Spies, Gerald Kehr, Klaus Bergander, +3

Dalton Transactions

Direct Dearomatization of Pyridines via an Energy-Transfer-Catalyzed Intramolecular [4+2] Cycloaddition

Jiajia Ma, Felix Strieth‐Kalthoff, Toryn Dalton, +5

Chem

EngineeringHeterocyclicDirect DearomatizationOrganic ChemistryCatalysis +3

Reaction of the Lewis Acid Tris(pentafluorophenyl)borane with a Phosphorus Ylide:  Competition between Adduct Formation and Electrophilic and Nucleophilic Aromatic Substitution Pathways

Steve Döring, Gerhard Erker, Roland Fröhlich, +2

Organometallics

Inorganic ChemistryAdduct FormationEngineeringBiochemistryCompound 4 +13