21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T4cf,Photoelectrochemical nitrate reduction reaction (PEC NIRR) could convert the harmful pollutant nitrate (NO₃^-) to high-value-added ammonia (NH₃) under mild conditions. However, the catalysts are currently hindered by the low catalytic activity and slow kinetics. Here, we reported a heterostructure composed of CeO₂ and BiVO₄, and the "frustrated Lewis pairs (FLPs)" concept was introduced for understanding the role of Lewis acids and Lewis bases on PEC NIRR. The electron density difference maps indicated that FLPs were significantly active for the adsorption and activation of NO₃^-. Furthermore, carbon (C) improved the carrier transport ability and kinetics, contributing to the NH₃ yield of 21.81 μg h^-1 cm^-2. The conversion process of NO₃^- to NH₃ was tracked by ¹⁵NO₃^- and ¹⁴NO₃^- isotopic labeling. Therefore, this study demonstrated the potential of CeO₂-C/BiVO₄ for efficient PEC NIRR and provided a unique mechanism for the adsorption and activation of NO₃^- over FLPs.

#	Concept	H-Index	Publications	Citations
1	Engineering	8	8	406
2	Chemical Engineering	7	7	368
3	Materials Science	7	7	321
4	Chemistry	5	5	316
5	Applied Physics	3	3	150

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