21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/7938a53b43dec130.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T4bc,Controlling the growth of metal-organic frameworks (MOFs) at the micro-/nanoscopic scale will result in new physical properties and novel functions into the materials without changing the chemical identities and the characteristic features of the MOFs themselves. Herein, we report a facile approach to synthesize a series of MOFs [Co-MOF, Co_xNi_y-MOFs (x and y represent the molar ratio of Co²⁺ and Ni²⁺ and x/y = 1:1, 1:5, 1:10, 1:15, and 1:20), and Ni-MOF] with a one-dimensional micro-/nanoscaled rod-like architecture. From Co-MOF to Co_xNi_y-MOFs to Ni-MOF, the diameters of the rods turn to be spindly with the increase of Ni²⁺ content which will facilitate the supercapacitor performances. Interestingly, Co₁Ni₂₀-MOF exhibits a highest specific capacity of 597 F g^-1 at 0.5 A g^-1 and excellent cycle performance (retained 93.59% after 4000 cycles) among these MOF materials owing to its micro-/nanorod structure with a smaller diameter and the synergy effect between the optimum molar ratio of Co²⁺ and Ni²⁺.23:T506,The rational exploration of hybrid materials with well-defined compositions and structures/morphologies is essential for achieving high-performance electrodes for supercapacitors. Here, in situ dispersion and anchoring of NiCoP nanoparticles (NPs) on a bimetal-organic framework (Co₁Ni₂-MOF) by a controllable partial phosphorization approach are reported. The phosphating temperature and time significantly affect the specific capacitance of NiCoP/Co₁Ni₂-MOF-X-Y (where X and Y represent the phosphating temperature and time, respectively). Co₁Ni₂-MOF provides anchoring sites for confining NiCoP NPs, effectively improving the stability of NiCoP NPs. Highly dispersed NiCoP NPs facilitate OH^- adsorption, boosting the redox reaction kinetics. NiCoP/Co₁Ni₂-MOF-350-2 with optimized phosphating conditions exhibits a high specific capacitance of 525 F g^-1 at 0.5 A g^-1, which is superior to that of the precursor of Co₁Ni₂-MOF. Moreover, a hybrid supercapacitor constructed with NiCoP/Co₁Ni₂-MOF-350-2 and activated carbon shows a high specific capacitance and outstanding long-term stability.24:T5ab,

#	Concept	H-Index	Publications	Citations
1	Chemistry	5	5	301
2	Engineering	4	4	147
3	Chemical Engineering	4	4	147
4	Materials Science	3	3	119
5	Battery Electrode Materials	1	1	67

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