Jeanne M. Sirovatka

Coenzyme B₁₂ Chemical Precedent Studies:  Probing the Role of the Imidazole Base-on Motif Found in B₁₂-Dependent Methylmalonyl-CoA Mutase

Jeanne M. Sirovatka, Richard G. Finke · Journal of the American Chemical Society · 1997 · 68 citations

Life Sciences, Biochemistry, Molecular Biology +17

Adocobinamide, the Base-off Analog of Coenzyme B₁₂ (Adocobalamin). 2.¹ Probing the “Base-on” Effect in Coenzyme B₁₂ via Cobalt−Carbon Bond Thermolysis Product and Kinetic Studies as a Function of Exogenous Pyridine Bases

Cheryl D. Garr, Jeanne M. Sirovatka, Richard G. Finke · Journal of the American Chemical Society · 1996 · 46 citations

Natural Sciences, Biochemistry, Chemistry +15

Coenzyme B₁₂ Axial-Base Chemical Precedent Studies. Adenosylcobinamide Plus Sterically Hindered Axial-Base Co−C Bond Cleavage Product and Kinetic Studies:  Evidence for the Dominance of Axial-Base Transition-State Effects and for Co−N(Axial-Base) Distance-Dependent, Competing σ and π Effects

Jeanne M. Sirovatka, Richard G. Finke · Inorganic Chemistry · 1999 · 39 citations

Life Sciences, Biochemistry, Molecular Biology +17

Molecular mechanics studies of coenzyme B12 complexes with constrained Co-N(axial-base) bond lengths: introduction of the universal force field (UFF) to coenzyme B12 chemistry and its use to probe the plausibility of an axial-base-induced, ground-state corrin butterfly conformational steric effect

Jeanne M. Sirovatka, Anthony K. Rappé, Richard G. Finke · Inorganica Chimica Acta · 2000 · 35 citations

Natural Sciences, Biochemistry, Chemistry +15