Tomohiro Adachi

Cationic rhodium(<scp>I</scp>) complexes of 1,4,8,11-tetrathiacyclotetradecane ([14]aneS₄) and the 6,6,13,13-tetramethyl analogue (Me₄[14]aneS₄). Preparation of two conformers, X-ray crystal structure of {Rh[14]aneS₄}₂Cl₂·MeCN, and conformational effect on the nucleophilicity of the rhodium(<scp>I</scp>) ion

Toshikatsu Yoshida, Tatsuo Ueda, Tomohiro Adachi et al. · Journal of the Chemical Society Chemical Communications · 1985 · 20 citations

Natural Sciences, Chemistry, Medicinal Chemistry +15

Reaction of a molybdenum(0) dinitrogen complex containing a crown thioether with isocyanides. Formation of the extensively bent PhNC complex trans-Mo(PhNC)2(Me8[16]aneS4) and facile dealkylation of ButNC to give trans-Mo(CN)2(Me8[16]aneS4)(Me8[16]aneS4= 3,3,7,7,11,11,15,15-octamethyl-1,5,9,13-tetrathiacyclohexadecane)

Tomohiro Adachi, Nobuyoshi Sasaki, Tatsuo Ueda et al. · Journal of the Chemical Society Chemical Communications · 1989 · 18 citations

Natural Sciences, Chemistry, Crystal Structure +11

Conversion of a molybdenum nitride to the amide and thence to an oxide and ammonia, reactions involving formal 1,3-prototropic shifts. X-Ray structures of trans-[Mo(NH2)(OH)(dppe)2][OTf]2 and trans-[MoO(OMe)(dppe)2][BPh4](dppe = Ph2PCH2CH2PPh2; OTf = CF3SO3)

Tomohiro Adachi, David L. Hughes, Saad K. Ibrahim et al. · Journal of the Chemical Society Chemical Communications · 1995 · 15 citations

Natural Sciences, Chemistry, Crystal Structure +12