We report elevated levels of gaseous inorganic chlorinated and nitrogenated compounds in indoor air while cleaning with a commercial bleach solution during the House Observations of Microbial and Environmental Chemistry field campaign in summer 2018. Hypochlorous acid (HOCl), chlorine (Cl₂), and nitryl chloride (ClNO₂) reached part-per-billion by volume levels indoors during bleach cleaning-several orders of magnitude higher than typically measured in the outdoor atmosphere. Kinetic modeling revealed that multiphase chemistry plays a central role in controlling indoor chlorine and reactive nitrogen chemistry during these periods. Cl₂ production occurred via heterogeneous reactions of HOCl on indoor surfaces. ClNO₂ and chloramine (NH₂Cl, NHCl₂, NCl₃) production occurred in the applied bleach via aqueous reactions involving nitrite (NO₂^-) and ammonia (NH₃), respectively. Aqueous-phase and surface chemistry resulted in elevated levels of gas-phase nitrogen dioxide (NO₂). We predict hydroxyl (OH) and chlorine (Cl) radical production during these periods (10⁶ and 10⁷ molecules cm^-3 s^-1, respectively) driven by HOCl and Cl₂ photolysis. Ventilation and photolysis accounted for <50% and <0.1% total loss of bleach-related compounds from indoor air, respectively; we conclude that uptake to indoor surfaces is an important additional loss process. Indoor HOCl and nitrogen trichloride (NCl₃) mixing ratios during bleach cleaning reported herein are likely detrimental to human health.

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