21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T4f8,Herein, we explore a general Cu_2-x S nanocube template-assisted and reverse cation exchange-mediated growth strategy for fabricating hollow multinary metal sulfide. Unlike the traditional cation exchange method controlled by the metal sulfide constant, the introduction of tri-n-butylphosphine (TBP) can reverse cation exchange to give a series of hollow metal sulfides. A variety of hollow multinary metal sulfide cubic nanostructures has been demonstrated while preserving anisotropic shapes to the as-synthesized templates, including binary compounds (CdS, ZnS, Ag₂ S, PbS, SnS), ternary compound (CuInS₂ , Zn_x Cd_1-x S), and quaternary compound (single-atom platinum anchored Zn_x Cd_1-x S; Zn_x Cd_1-x S-Pt₁ ). Experimental and density functional theory (DFT) calculations show that the hollow metal sulfide semiconductors obtained could significantly improve the separation and migration of photogenerated electron-hole pairs. Owing to the efficient charge transfer, the Zn_x Cd_1-x S-Pt₁ exhibited outstanding photocatalytic performance of CO₂ to CO, with the highest CO generation rate of 75.31 μmol h^-1 .23:T558,

#	Concept	H-Index	Publications	Citations
1	Engineering	2	2	120
2	Chemistry	2	2	120
3	Natural Sciences	1	1	25
4	Chemical Engineering	1	1	95
5	Materials Science	1	1	25

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