James A. Gavney

Diphosphines with natural bite angles near 120.degree. increase selectivity for n-aldehyde formation in rhodium-catalyzed hydroformylation

Charles P. Casey, Gregory T. Whiteker, Margaret G. Melville et al. · Journal of the American Chemical Society · 1992 · 386 citations

Engineering, Increase Selectivity, Altmetric Attention Score +16

Reactions of the [Ni6(CO)12]2- dianion with stibine and bismuthine reagents: synthesis and stereophysical characterization of the [Ni10(SbPh)2(CO)18]2- dianion containing a noncentered icosahedral Ni10Sb2 core and Ni2(CO)4(μ2-Ph2SbOSbPh2)2 containing a centrosymmetric eight-membered (NiSbOSb)2 ring

Robert E. DesEnfants, James A. Gavney, Randy K. Hayashi et al. · Journal of Organometallic Chemistry · 1990 · 40 citations

Materials Science, Inorganic Chemistry, Bismuthine Reagents +7

Synthesis, chromatographic separation, and stereophysical analysis of the homologous [Ni12-x(PMe)x(CO)24-3x]2- series (x = 2, 3, 4) containing noncentered Ni12-xPx icosahedral cages and the [Ni10(.mu.5-PMe)2(.mu.4-PMe)5(CO)10]2- dianion containing a structurally unprecedented heptacapped pentagonal prismatic metal cage: structural, spectroscopic, and electrochemical consequences due to replacement of Ni(CO)3 fragments with electronically equivalent (isolobal) PMe fragments

David F. Rieck, James A. Gavney, Richard Lawrence Norman et al. · Journal of the American Chemical Society · 1992 · 35 citations

Materials Science, Inorganic Chemistry, Stereophysical Analysis +13

Syntheses, x-ray crystal structures, and fluxional behavior of the clusters Cp*3Co3(.mu.2-CO)(.mu.3-CO)(.mu.-H)2, Cp*3Co3(.mu.-H)(.mu.3-.eta.2-HC:NCMe3), and Cp*3Co3(.mu.2-H)(.mu.3-.eta.2-HC:NCMe2CH2Me)

Charles P. Casey, Ross A. Widenhoefer, Susan L. Hallenbeck et al. · Organometallics · 1994 · 21 citations

Materials Science, Inorganic Chemistry, X-ray Crystallography +12

Rearrangement of an allyl vinyl rhenium complex to a rhenium allyl vinyl ketone complex via two consecutive concerted organometallic rearrangements

Charles P. Casey, Paul C. Vosejpka, James A. Gavney · Journal of the American Chemical Society · 1990 · 16 citations

Chemical Engineering, Novel Organocatalysts, Engineering +9