Triazolium-based ionic liquids (T1, T2 and T3) with or without terminal hydroxyl groups were prepared via Cu(i) catalysed azide-alkyne click chemistry and their properties were investigated using various technologies. The hydroxyl groups obviously affected their physicochemical properties, where with a decrease in the number of hydroxyl groups, their stability and conductivity were enhanced. T1, T2 and T3 showed relatively high thermal stability, and their electrochemical stability windows (ESWs) were 4.76, 4.11 and 3.52 V, respectively. T1S-20 was obtained via the addition of zinc trifluoromethanesulfonic acid (Zn(CF₃SO₃)₂) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) to T1, displaying conductivity and ESW values of 1.55 × 10^-3 S cm^-1 and 6.36 V at 30 °C, respectively. Subsequently, a Zn/Li₃V₂(PO₄)₃ battery was assembled using T1S-20 as the electrolyte and its performances at 30 °C and 80 °C were investigated. The battery showed a capacity of 81 mA h g^-1 at 30 °C, and its capacity retention rate was 89% after 50 cycles. After increasing the temperature to 80 °C, its initial capacity increased to 111 mA h g^-1 with a capacity retention rate of 93.6% after 100 cycles, which was much higher than that of the aqueous electrolyte (WS-20)-based zinc ion battery (71.8%). Simultaneously, the T1S-20 electrolyte-based battery exhibited a good charge/discharge efficiency, and its Coulomb efficiency was 99%. Consequently, the T1S-20 electrolyte displayed a better performance in the Zn/Li₃V₂(PO₄)₃ battery than that with the aqueous electrolyte, especially at high temperature.

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