Asymmetric Epoxidations with H₂O₂ on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study

Oleg Y. Lyakin, Roman V. Ottenbacher, Konstantin P. Bryliakov, +1

ACS Catalysis

EngineeringChiral BipyrrolidineMn AminopyridineAsymmetric EpoxidationsOrganic Chemistry +15

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

Oleg Y. Lyakin, Konstantin P. Bryliakov, George J. P. Britovsek, +1

Journal of the American Chemical Society

Epr Spectroscopic TrappingEngineeringSelective Hydrocarbon OxidationChemistryRedox Biology +14

Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features

Marina V. Kirillova, Yuriy N. Kozlov⊗, Lidia S. Shul’pina, +5

Journal of Catalysis

Chemical EngineeringEngineeringTriethanolaminate ComplexOrganic ChemistryCatalysis +8

EPR, ¹H and ²H NMR, and Reactivity Studies of the Iron–Oxygen Intermediates in Bioinspired Catalyst Systems

Oleg Y. Lyakin, Konstantin P. Bryliakov, Evgenii P. Talsi

Inorganic Chemistry

EPR Spectroscopic Detection of the Elusive Fe^V═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes

Oleg Y. Lyakin, Alexandra M. Zima, Denis G. Samsonenko⧫, +2

ACS Catalysis

Inorganic ChemistryChemical EngineeringEpr Spectroscopic DetectionSelective Catalytic OxofunctionalizationsEpr Spectroscopic Study +13

Non-heme oxoiron(V) intermediates in chemo-, regio- and stereoselective oxidation of organic substrates

Oleg Y. Lyakin, Konstantin P. Bryliakov, Evgenii P. Talsi

Coordination Chemistry Reviews

Stereoselective OxidationChemical EngineeringEngineeringNon-heme OxoironOrganic Chemistry +5

In Situ EPR Monitoring of Chromium Species Formed during Cr−Pyrrolyl Ethylene Trimerization Catalyst Formation

Igor Y. Skobelev, Valentina N. Panchenko, Oleg Y. Lyakin, +3

Organometallics

Materials ScienceSitu Epr MonitoringEthylene Trimerization ActivityEngineeringCatalytic Process +10

Iron-Catalyzed Enantioselective Epoxidations with Various Oxidants: Evidence for Different Active Species and Epoxidation Mechanisms

Alexandra M. Zima, Oleg Y. Lyakin, Roman V. Ottenbacher, +2

ACS Catalysis

EngineeringOrganic ChemistryIron ComplexesDeoxygenationChemistry +15

Dramatic Effect of Carboxylic Acid on the Electronic Structure of the Active Species in Fe(PDP)-Catalyzed Asymmetric Epoxidation

Alexandra M. Zima, Oleg Y. Lyakin, Roman V. Ottenbacher, +2

ACS Catalysis

Asymmetric EpoxidationLarge G-factor AnisotropyChemical EngineeringCarboxylic AcidValproic Acid +13

Direct Evaluation of the Reactivity of Nonheme Iron(V)–Oxo Intermediates toward Arenes

Oleg Y. Lyakin, Alexandra M. Zima, Nikolay V. Tkachenko, +2

ACS Catalysis

Oxygen Reduction ReactionInorganic ChemistryChemical EngineeringEngineeringNonheme Iron +9