A soil that was historically contaminated with Aqueous Film Forming Foam (AFFF) was dry sieved into size fractions representative of those produced during soil washing. Batch sorption tests were then conducted to investigate the effect of soil parameters on in situ per- and polyfluoroalkyl substances (PFAS) sorption of these different size fractions: < 0.063 mm, 0.063 to 0.5 mm, 0.5 to 2 mm, 2 to 4 mm, 4 to 8 mm, and soil organic matter residues (SOMR). PFOS (513 ng/g), 6:2 FTS (132 ng/g) and PFHxS (58 ng/g) were the most dominant PFAS in the AFFF contaminated soil. Non-spiked, in situ K_d values for 19 PFAS ranged from 0.2 to 138 L/Kg (log K_d -0.8 to 2.14) for the bulk soil and were dependant on the head group and perfluorinated chain length (spanning C₄ to C₁₃). The K_d values increased with decreasing grain size and increasing organic carbon content (OC), which were correlated to each other. For example, the PFOS K_d value for silt and clay (< 0.063 mm, 17.1 L/Kg, log K_d 1.23) were approximately 30 times higher compared to the gravel fraction (4 to 8 mm, 0.6 L/Kg, log K_d -0.25). The highest PFOS K_d value (116.6 L/Kg, log K_d 2.07) was found for the SOMR fraction, which had the highest OC content. K_oc values for PFOS ranged from 6.9 L/Kg (log K_oc 0.84) for the gravel fraction to 1906 L/Kg (log K_oc 3.28) for the silt and clay, indicating that the mineral composition of the different size fractions also influenced sorption. The results here emphasize the need to separate coarse-grained fractions and fine-grained fractions, and in particular the SOMR, to optimize the soil washing process. Higher K_d values for the smaller size fractions indicate that coarser soils are better suited for soil washing.

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