Gerhard Simchen

Trialkylsilyl Perfluoroalkanesulfonates: Highly Reactive Silylating Agents and Lewis Acids in Organic Synthesis

H. EMDE, Dietmar Domsch, Harry Feger et al. · Synthesis · 1982 · 230 citations

Engineering, Lewis Acids, Fluorous Synthesis +5

Anionic O → C Rearrangements in Trialkylsiloxy‐benzenes and Trialkylsiloxypyridines

Gerhard Simchen, Jörg Pfletschinger · Angewandte Chemie International Edition in English · 1976 · 43 citations

Organic Chemistry, Chemistry, Heterocycle Chemistry

β-silylation of N-alkylpyrroles, experimental support of theoretical calculations

M. W. MAJCHRZAK, Gerhard Simchen · Tetrahedron · 1986 · 28 citations

Organic Chemistry, Enantioselective Synthesis, Theoretical Calculations +1

Freidel-crafts acylation of 1-tert-butyldimethylsilylpyrrole, a very short and simple route to 3-substituted pyrroles.

Gerhard Simchen, Michal W. Majchrzak · Tetrahedron Letters · 1985 · 27 citations

Freidel-crafts Acylation, 3-Substituted Pyrroles, Engineering +7

Synthese von Keten-<i>O</i>-trimethylsilyl-<i>S</i>-alkyl-monothioacetalen

Gerhard Simchen, W. WEST · Synthesis · 1977 · 24 citations

Organic Chemistry, Synthetic Chemistry, Chemistry