Methyl orange dye (MO) is one of the azo dyes, which is not only difficult to degrade but also hazardous to human health, therefore, it is necessary to develop an efficient photocatalyst to degrade MO. In this paper, a facile and low-cost elemental doping method was used for the surface modification of Ti₃C₂ MXene, i.e., nitrogen-doped titanium carbide was used as the nitrogen source, and the strategy of combining solvent heat treatment with non-in situ nitrogen doping was used to prepare N-Ti₃C₂ MXene two-dimensional nanomaterials with high catalytic activity. It was found that the catalytic efficiency of N-Ti₃C₂ MXene materials was enhanced and improved compared to the non-doped Ti₃C₂ MXene. In particular, N-Ti₃C₂ 1:8 MXene showed the best photo-catalytic ability, as demonstrated by the fact that the N-Ti₃C₂ 1:8 MXene material successfully degraded 98.73% of MO (20 mg/L) under UV lamp irradiation for 20 min, and its catalytic efficiency was about ten times that of Ti₃C₂ MXene, and the N-Ti₃C₂ photo-catalyst still showed good stability after four cycles. This work shows a simplified method for solvent heat-treating non-in situ nitrogen-doped Ti₃C₂ MXene, and also elaborates on the photo-catalytic mechanism of N-Ti₃C₂ MXene, showing that the high photo-catalytic effect of N-Ti₃C₂ MXene is due to the synergistic effect of its efficient charge transfer and surface-rich moieties. Therefore, N-Ti₃C₂ MXene has a good prospect as a photo-catalyst in the photocatalytic degradation of organic pollutants.

Quanhao Deng

Publications