21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T487,It is vitally important to develop highly active, robust and low-cost transition metal-based electrocatalysts for overall water splitting in neutral solution especially at large current density. In this work, amorphous Mo-doped NiS_0.5 Se_0.5 nanosheets@crystalline NiS_0.5 Se_0.5 nanorods (Am-Mo-NiS_0.5 Se_0.5 ) was synthesized using a facil one-step strategy. In phosphate buffer saline solution, the Am-Mo-NiS_0.5 Se_0.5 shows tiny overpotentials of 48 and 209 mV for hydrogen evolution reaction (HER), 238 and 514 mV for oxygen evolution reaction (OER) at 10 and 1000 mA cm^-2 , respectively. Moreover, Am-Mo-NiS_0.5 Se_0.5 delivers excellent stability for at least 300 h without obvious degradation. Theoretical calculations revealed that the Ni sites in the defect-rich amorphous structure of Am-Mo-NiS_0.5 Se_0.5 owns higher electron state density and strengthened the binding energy of H₂ O, which will optimize H adsorption/desorption energy barriers and reduce the adsorption energy of OER determining step.23:T4b2,The sluggish kinetics and mutual interference of oxygen evolution and reduction reactions in the air electrode resulted in large charge/discharge overpotential and low energy efficiency of Zn-air batteries. In this work, we designed a breathing air-electrode configuration in the battery using P-type Ca₃ Co₄ O₉ and N-type CaMnO₃ as charge and discharge thermoelectrocatalysts, respectively. The Seebeck voltages generated from thermoelectric effect of Ca₃ Co₄ O₉ and CaMnO₃ synergistically compensated the charge and discharge overpotentials. The carrier migration and accumulation on the cold surface of Ca₃ Co₄ O₉ and CaMnO₃ optimized the electronic structure of metallic sites and thus enhanced their intrinsic catalytic activity. The oxygen evolution and reduction overpotentials were enhanced by 101 and 90 mV, respectively, at temperature gradient of 200 °C. The breathing Zn-air battery displayed a remarkable energy efficiency of 68.1 %. This work provides an efficient avenue towards utilizing waste heat for improving the energy efficiency of Zn-air battery.24:T601,

#	Concept	H-Index	Publications	Citations
1	Engineering	3	3	61
2	Chemistry	2	2	32
3	Natural Sciences	1	1	21
4	Chemical Engineering	1	1	21
5	Materials Science	1	1	11

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