Stephen A. Brew

Alkylidyne(carbaborane) complex of the group 6 metals. 3. Facile transformations of 12- and 13-vertex tungstacarborane polyhedra reversible. Framework rearrangement and acid-induced ejection of a cage vertex

Stephen A. Brew, Nicholas Carr, John C. Jeffery et al. · Journal of the American Chemical Society · 1992 · 31 citations

Natural Sciences, Chemistry, Materials Science +15

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 107. Reactions of diphenylphosphine with molybdenumtungsten dimetal complexes; crystal structures of [MoW(µ-PPh₂){µ-C(OH)C(C₆H₄Me-4)}-(CO)(η⁷-C₇H₇)(η⁵-C₂B₉H₁₁)]and[MoW(µ-PPh₂)(CO)₃(η⁵-C₉H₇){η⁵-C₂B₉H₈(CH₂C₆-H₄Me-4)Me₂}]

Stephen A. Brew, Stephen J. Dossett, John C. Jeffery et al. · Journal of the Chemical Society Dalton Transactions · 1990 · 22 citations

Natural Sciences, Chemistry, Crystal Structure +16

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 111. Protonation of the salts [NEt₄][M(CR)(CO)₂(η^x-C₂B_nH_nMe₂)](M = Mo or W; R = Me or C₆H₄Me-4; x= 5, n= 9; x= 6, n= 10) in the presence of the alkylidynemetal compounds [M(CR)(CO)₂(η-C₅H₅)]; crystal structures of [W₂(µ-CMe)(CO)₃{η⁵-C₂B₉H₈(CH₂C₆H₄Me-4)Me₂}(η-C₅H₅)], [W₂(µ-CC₆H₄Me-4)(CO)₃(η⁵-C₂B₉H₉Me₂)(η-C₅H₅)] and [MoW(µ-CC₆H₄Me-4)(CO)₂(PMe₃)(η⁶-C₂B₁₀H₁₀Me₂)(η⁵-C₅H₅)]

Stephen A. Brew, Nicholas Carr, Mark D. Mortimer et al. · Journal of the Chemical Society Dalton Transactions · 1991 · 20 citations

Natural Sciences, Chemistry, Crystal Structure +14

Alkylidyne(carbaborane) complexes of the Group 6 metals. Part 6. exo-nido-Tungstacarbaborane compounds

Stephen A. Brew, John C. Jeffery, Mark D. Mortimer et al. · Journal of the Chemical Society Dalton Transactions · 1992 · 16 citations

Natural Sciences, Chemistry, Materials Science +17

Protonation of alkylidyne(carbaborane)tungsten complexes: framework rearrangement of an icosahedral cage at an unprecedentedly low temperature

Stephen A. Brew, J.C. Jeffrey, Massimino U. Pilotti et al. · Journal of the American Chemical Society · 1990 · 12 citations

Natural Sciences, Chemistry, Materials Science +14