John Gavenonis

Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me₃C₆H₂)₂C₆H₃N]²^-([Ar*N]²^-). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO₂CF₃)], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand

John Gavenonis, T. Don Tilley · Organometallics · 2002 · 114 citations

Natural Sciences, Chemistry, Inorganic Chemistry +14

Reversible Intramolecular Hydride Transfer between Tantalum and an Aromatic Ring:  An η⁵-Cyclohexadienyl Complex as a Masked Hydride

John Gavenonis, T. Don Tilley · Journal of the American Chemical Society · 2002 · 70 citations

Natural Sciences, Chemistry, Catalysis +13

Neutral and Anionic Silyl Hydride Derivatives of the Tantalum Imido Fragment Cp*(DippN)Ta (Cp* = η⁵-C₅Me₅; Dipp = 2,6-ⁱPr₂C₆H₃). Reactive σ-Bonds and Intramolecular C−H Bond Activations Involving the Silyl Ligands

Urs Burckhardt, Gary L. Casty, John Gavenonis et al. · Organometallics · 2002 · 59 citations

Natural Sciences, Chemistry, Inorganic Chemistry +12

Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(Ar^MesN)Ta (Cp* = η⁵-C₅Me₅; Ar^Mes = 2,6-(2,4,6-Me₃C₆H₂)₂C₆H₃) and Cp*(Ar^TripN)Ta (Ar^Trip = 2,6-(2,4,6-ⁱPr₃C₆H₂)₂C₆H₃)

John Gavenonis, T. Don Tilley · Organometallics · 2003 · 55 citations

Natural Sciences, Chemistry, Inorganic Chemistry +8

Synthesis and reactivity of bis(heptamethylindenyl) yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: crystal structure of Ind*2YCl(THF)

John Gavenonis, T. Don Tilley · Journal of Organometallic Chemistry · 2004 · 25 citations

Natural Sciences, Chemistry, Materials Science +12