Robert Zoet

Organonickel(II) complexes of the tridentate monoanionic ligand o,o'-bis[(dimethylamino)methylphenyl (N-C-N). Syntheses and the x-ray crystal structure of the stable nickel(II) formate [Ni(N-C-N)O2CH]

David M. Grove, Gerard van Koten, Henk J. C. Ubbels et al. · Organometallics · 1984 · 94 citations

Natural Sciences, Chemistry, Inorganic Chemistry +11

Synthesis and characterization of two isomers of decacarbonyl (1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behavior of Os3(CO)10(i-Pr-Pr-DAB(4e)) and of the 50e cluster Os3(CO)10(c-Pr-DAB(6e)) containing a 4e donor .rho.,.rho.-N,N' and a 6e donor .rho.-N, .mu.2-N', .eta.2-C:N' bonded R-DAB ligand, respectively.

Robert Zoet, Johann T. B. H. Jastrzebski, Gerard van Koten et al. · Organometallics · 1988 · 26 citations

Natural Sciences, Biochemistry, Chemistry +5

Synthesis of heterodinuclear FeRu(CO)6(R-DAB(6e))(R-DABRNC(H)C(H)NR) Part XV. Comparison of the reactivities of heterodinuclear FeRu(CO)6(R-DAB(6e)) and homodinuclear analogues M2(CO)6(R-DAB(6e)) (M = Fe, Ru). Single-crystal x-ray structures of FeRu(CO)6(i-Pr-DAB(6e)) and FeRu(CO)5(i-Pr-DAB(4e))(C3H4)

Robert Zoet, G. Van Koten, Fred Muller et al. · Inorganica Chimica Acta · 1988 · 23 citations

Natural Sciences, Biochemistry, Chemistry +11

Stereoselective trans addition of D2 to the coordinated RN=C(R1)C(H)=NR ligand in FeRu(CO)6(R-DAB;R1,H(6e)) to afford FeRu(CO)6(.mu.,.mu.'-N(R)CR1DCHDN(R)) (R = iso-Pr, R1 = Me, H; R = p-Tol, R1 = H). Kinetic 1H NMR studies of the hydrogenation at hydrogen pressures between 1 and 70 bar. Single-crystal x-ray structure determinations of FeRu(CO)6(.mu.,.mu.'-N(R)CH2CR1HN(R)) (R = iso-Pr and R1 = H, Me)

Robert Zoet, Cornelis J. Elsevier, Gerard van Koten et al. · Organometallics · 1989 · 19 citations

Natural Sciences, Biochemistry, Chemistry +10

Activation of an aliphatic carbon-hydrogen bond at room temperature. Conversion on a cluster of a stable .sigma.-bonded alkyl group to a .mu.2-alkylidene ligand. Synthesis and crystal structure determination of HOs3(6-CH2C5H3N-2-C(H):N-iso-Pr)(CO)9 and H2Os3(6-CHC5H3N-2-C(H):N-iso-Pr)(CO)8

Robert Zoet, Gerard van Koten, Kees Vrieze et al. · Organometallics · 1988 · 16 citations

Natural Sciences, Chemistry, Inorganic Chemistry +10