Cocurrent biological nitrification and denitrification in wastewater treatment

Abstract

Repetitive conditioning of recycle activated sludge (RAS) under strict anaerobic conditions gradually changes the products of ammonia oxidation from nitrite and nitrate to nitrous oxide (N 2 O) and nitrogen (N 2 ). Nitrite inhibits oxygen respiration of anaerobically conditioned sludge; biochemical oxygen demand (BOD) is then oxidized by nitrite, which is reduced to N 2 O and N 2 . When anaerobic RAS conditioning is initially imposed on a nitrifying system, Nitrobacter species continue to oxidize nitrite to nitrate and thus reduce the nitrite available to oxidize BOD. However, Nitrobacter in the mixed liquor gradually tend to wash out because the sole source of Nitrobacter energy, the oxidation of nitrite to nitrate, is diminished to the extent that nitrite is reduced. Incorporation of an RAS conditioning zone to the activated‐sludge process results in evolution of a nonfilamentous biomass, which affects both cocurrent biological nitrification and denitrification (CBND) and biological phosphorus removal (BPR). The initial feed zone may be either aerobic or anaerobic. A final anoxic denitrification zone is desirable for removal of residual nitrite plus nitrate (NO x ) from aeration effluent. Nitrous oxide, the main reaction product of CBND, promotes both global warming and destruction of the stratospheric ozone layer.