Inorganic Chemistry · 2015 · 58 citations · 43 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOrganic ChemistrySurface ScienceCatalytic MaterialsInorganic SynthesisOrganic SynthesisPorous MaterialsSurface Functionalization Of NanomaterialsClick Chemistry FunctionalizationMetal-organic Framework SynthesisMetal-organic FrameworksTransition-metal-catalyzed Functionalization
Herein, we report the synthesis and postsynthetic modification of a novel alkyne-tagged zirconium metal-organic framework, UiO-68-alkyne. The alkynyl groups in the pore surface were subjected to a "click" reaction, achieving quantitative conversion and maintaining the crystallinity of the framework.
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa, Kyle E. Cordova, M. O’Keeffe et al. · Science · 2013 · 16.5K citations