Energy & Environmental Science · 2025 · 15 citations · 51 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryInorganic ChemistryBattery MaterialsBattery TechnologyCathode MaterialsElectrochemical CellsElectrochemical Energy StorageElectrode MaterialsBattery DegradationBattery Degradation MechanismsDegradationElectrode Degradation MechanismsSide ReactionsSodium-ion BatteriesSodium-ion Battery ElectrodesSodium-ion Cathodes
Fe(CN) 6 4− vacancies in Prussian blue analog cathodes hinder Na + transport and trigger side reactions, causing capacity loss. High-quality PBA with fewer defects mitigates this, achieving 81.7% capacity retention over 900 cycles.
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