Advancement in Research on Silicon/Carbon Composite Anode Materials for Lithium-Ion Batteries

Abstract

Silicon stands out as an exceptionally viable anode material, distinguished by its substantial capacity, plentiful natural reserves, eco-friendliness, and favorable low working potential. Nonetheless, the material’s pronounced volume fluctuations readily induce particle fragmentation, detachment of active components, and repeated disruption of the solid electrolyte interphase (SEI) layer. These factors contribute to a shortened cycle life and rapid capacity fading, thus hindering its practical application. The carbon composite approach can efficiently counteract these issues by capitalizing on silicon’s high capacity and employing carbon as a cushioning agent to diminish volume swelling, thus enhancing the deployment of silicon-based anode materials. This paper offers an exhaustive examination of the lithiation processes involved in Si/C anodes and delves into the strategic utilization of diverse carbon materials, including graphite, graphene, graphdiyne, carbon nanotubes, carbon fibers, MXenes, pitch, heteroatom-doped polymers, biomass-derived carbon, carbon-containing gas-derived carbon, MOFs, and g-C3N4 to advance the application of silicon in lithium-ion battery (LIB) anodes. Overall, this paper concentrates on summarizing the current research status and technological advancement and juxtaposes the merits and demerits of various carbon sources in Si/C anodes, thus providing a comprehensive assessment and forward-looking perspective on their future development.