Concepedia

Robust interphase derived from a dual-cation ionic liquid electrolyte enabling exceptional stability for nickel-rich layered cathodes

Fanglin Wu, Haolin Tang, Jian Wang, Xilai Xue, Thomas Diemant, Shan Fang, Huihua Li, Ziyuan Lyu, Hao Li, En Xie,

Energy & Environmental Science · 2025 · 11 citations · 56 references

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Concepts

Abstract

A dual-cation-based ionic liquid electrolyte with NaPF 6 additive, was designed for nickel-rich cathodes in Li-metal battery. The formed uniform and robust electrode/electrolyte interphases enables the exceptional 1500-cycle life of Li||NCM83 cells.

References

56

Efficient iterative schemes for<i>ab initio</i>total-energy calculations using a plane-wave basis set

Georg Kresse, J. Furthmüller · Physical review. B, Condensed matter · 1996 · 120.5K citations

, , +15

High-nickel layered oxide cathodes for lithium-based automotive batteries

Wangda Li, Evan M. Erickson, Arumugam Manthiram · Nature Energy · 2020 · 1.7K citations · Full text

, , +12

The COMPASS force field: parameterization and validation for phosphazenes

Huai Sun, Pengyu Ren, Joel Fried · Computational and Theoretical Polymer Science · 1998 · 1.5K citations

, , +7

Quantifying inactive lithium in lithium metal batteries

Chengcheng Fang, Jinxing Li, Minghao Zhang et al. · Nature · 2019 · 1.4K citations · Full text

, , +14

An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes

Sufu Liu, Xiao Ji, Nan Piao et al. · Angewandte Chemie International Edition · 2020 · 589 citations · Full text

, , +17