Concepedia

Engineering geometric metamorphosis in {P<sub>6</sub>M<sub>2</sub>Mo<sub>16</sub>O<sub>73</sub>}-based high-nuclearity metal superclusters: from tetrahedral to square assemblies <i>via</i> topological transformations

Xiaoyan Zhang, Hui Li, Na Xu, Xiuli Wang

Inorganic Chemistry Frontiers · 2025 · 41 citations · 42 references

DOI

Concepts

Abstract

The precision engineering of the molecular framework has synthesized two superclusters based on the {Sr⊂P 6 M 2 Mo 16 O 73 } motif, which exhibit closely related topological structures: Co12Sr4Mo80P36 and Na4Ni23Sr4Mo88P52.

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