Concepedia

Synergistic crystalline catalysts assembled with Wells–Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C–H bond oxidation

Ze-Xuan Liu, Shuai Li, Yuan‐Yuan Ma, Zhangang Han

Inorganic Chemistry Frontiers · 2025 · 23 citations · 58 references

DOI

Concepts

Abstract

Two synergistic crystalline catalysts assembled with Wells–Dawson-type [P 2 W 18 O 62 ] 6− cluster and heterovalent Cu complexes were synthesized for benzylic C–H oxidation, with high DPM conversion and a distinct radical-mediated oxidation mechanism.

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