1f:T4c1,Rechargeable aqueous zinc-ion batteries (AZIBs) have captured a surge of interest in recent years as a promising alternative for scalable energy storage applications owing to the intrinsic safety, affordability, environmental benignity, and impressive electrochemical performance. Despite the facilitated development of this technology by many investigations, however, its smooth implementation is still plagued by inadequate energy density and undesirable life span, which calls for an efficient and controllable cathode storage chemistry. Here, this review focuses on the key bottlenecks by offering a comprehensive summary of representative cathode materials and comparatively analyzing their structural features and electrochemical properties. Then, we critically present several feasible electrode design strategies to guide future research activities from a fundamental perspective for high-energy-density and durable cathode materials mainly in terms of interlayer regulation, defect engineering, multiple redox reactions, activated two-electron reactions, and electrochemical activation and conversion. Finally, we outline the remaining challenges and future perspectives of developing high-performance AZIBs.20:T40e,The electrochemical performance of vanadium-oxide-based cathodes in aqueous zinc-ion batteries (ZIBs) depends on their degree of crystallinity and composite state with carbon materials. An in situ electrochemical induction strategy was developed to fabricate a metal-organic-framework-derived composite of amorphous V₂ O₅ and carbon materials (a-V₂ O₅ @C) for the first time, where V₂ O₅ is in an amorphous state and uniformly distributed in the carbon framework. The amorphous structure endows V₂ O₅ with more isotropic Zn²⁺ diffusion routes and active sites, resulting in fast Zn²⁺ transport and high specific capacity. The porous carbon framework provides a continuous electron transport pathway and ion diffusion channels. As a result, the a-V₂ O₅ @C composites display extraordinary electrochemical performance. This work will pave the way toward design of ZIB cathodes with superior rate performance.21:T515,Abstract Zinc‐ion batteries (ZIBs) have been extensively investigated and discussed as promising energy storage devices in recent years owing to their low cost, high energy density, inherent safety, and low environmental impact. Nevertheless, several challenges remain that need to be prioritized before realizing the widespread application of ZIBs. In particular, the development of zinc anodes has been hindered by many challenges, such as inevitable zinc dendrites, corrosion passivation, and the hydrogen evolution reaction (HER), which have severely limited the practical application of high‐performance ZIBs. This review starts with a systematic discussion of the origins of zinc dendrites, corrosion passivation, and the HER, as well as their effects on battery performance. Subsequently, we discuss solutions to the above problems to protect the zinc anode, including the improvement of zinc anode materials, modification of the anode–electrolyte interface, and optimization of the electrolyte. In particular, this review emphasizes design strategies to protect zinc anodes from an integrated perspective with broad interest rather than a view with limited focus. In the final section, comments and perspectives are provided for the future design of high‐performance zinc anodes. image

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