Hybrid Amorphous Cu(OH)₂/ZIF-67 as Oxygen Evolution Reaction Electrocatalysts for Anion-Exchange Membrane Water Electrolyzers

Abstract

The anion-exchange membrane water electrolyzer (AEM electrolyzer) is an advanced technology for the sustainable production of green hydrogen. However, its commercialization has been hindered by its relatively low performance, which necessitates the use of platinum group metal (PGM)-based electrocatalysts. Herein, we address this challenge by developing a composite material consisting of non-PGM-based amorphous Cu(OH) 2 and ZIF-67. The abundant defects in amorphous Cu(OH) 2 and the modification of the electronic structure, induced by the strong interaction between ZIF-67 and Cu(OH) 2, significantly enhance the catalytic performance of the oxygen evolution reaction (OER). The AEM electrolyzer equipped with Cu(OH) 2 @ZIF-100 demonstrates a higher performance (1.75 V cell at 1.0 A/cm 2 ) compared to those using RuO 2 (1.784 V cell at 1.0 A/cm 2 ) by reducing mass transport losses within the AEM electrolyzer.