Concepedia

Modular synthesis of divergent thiofunctionalized sulfoxonium ylides

Qiong Hu, Mei-Zhu Bao, Yuan-Jie Meng, Xinxing Liu, Wen‐Xuan Zou, Jialin Song, Jiaohang Wei, Dan‐Ting Shen, Xiaohui Cao, Shang‐Shi Zhang

Organic Chemistry Frontiers · 2024 · 10 citations · 48 references

DOI

Concepts

Abstract

A metal-free protocol for the modular synthesis of diverse α-thiofunctionalized-α′-carbonyl sulfoxonium ylides from sulfoxonium–iodonium hybrid ylides (I (III) /S (VI) -ylides) has been achieved.

References

48

Cross‐Coupling of α‐Carbonyl Sulfoxonium Ylides with C−H Bonds

Manuel Barday, Christopher Janot, Nathan R. Halcovitch et al. · Angewandte Chemie International Edition · 2017 · 256 citations · Full text

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Synthesis of Indoles and Pyrroles Utilizing Iridium Carbenes Generated from Sulfoxonium Ylides

Janakiram Vaitla, Annette Bayer, Kathrin H. Hopmann · Angewandte Chemie International Edition · 2017 · 236 citations · Full text

, , +17

Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

Shunxi Dong, Xiaohua Liu, Xiaoming Feng · Accounts of Chemical Research · 2022 · 235 citations

, , +10

A General Organocatalytic System for Electron Donor–Acceptor Complex Photoactivation and Its Use in Radical Processes

Eduardo de Pedro Beato, Davide Spinnato, Wei Zhou et al. · Journal of the American Chemical Society · 2021 · 231 citations · Full text

, , +16

Efficient Synthesis of Sulfur-Stereogenic Sulfoximines via Ru(II)-Catalyzed Enantioselective C–H Functionalization Enabled by Chiral Carboxylic Acid

Tao Zhou, Pu‐Fan Qian, Jun-Yi Li et al. · Journal of the American Chemical Society · 2021 · 221 citations

, , +10