The hydrogen evolution in Zn metal battery is accurately quantified by in situ battery-gas chromatography-mass analysis. The hydrogen fluxes reach 3.76 mmol h^-1 cm^-2 in a Zn//Zn symmetric cell in each segment, and 7.70 mmol h^-1 cm^-2 in a Zn//MnO₂ full cell. Then, a highly electronically insulating (0.11 mS cm^-1 ) but highly Zn²⁺ ion conductive (80.2 mS cm^-1 ) ZnF₂ solid ion conductor with high Zn²⁺ transfer number (0.65) is constructed to isolate Zn metal from liquid electrolyte, which not only prohibits over 99.2% parasitic hydrogen evolution but also guides uniform Zn electrodeposition. Precisely quantitated, the Zn@ZnF₂ //Zn@ZnF₂ cell only produces 0.02 mmol h^-1 cm^-2 of hydrogen (0.53% of the Zn//Zn cell). Encouragingly, a high-areal-capacity Zn@ZnF₂ //MnO₂ (≈3.2 mAh cm^-2 ) full cell only produces maximum hydrogen flux of 0.06 mmol h^-1 cm^-2 (0.78% of the Zn//Zn cell) at the fully charging state. Meanwhile, Zn@ZnF₂ //Zn@ZnF₂ symmetric cell exhibits excellent stability under ultrahigh current density and areal capacity (10 mA cm^-2 , 10 mAh cm^-2 ) over 590 h (285 cycles), which far outperforms all reported Zn metal anodes in aqueous systems. In light of the superior Zn@ZnF₂ anode, the high-areal-capacity aqueous Zn@ZnF₂ //MnO₂ batteries (≈3.2 mAh cm^-2 ) shows remarkable cycling stability over 1000 cycles with 93.63% capacity retained at ≈100% Coulombic efficiency.

	Year	Citations

References