Defect engineering is a proven method to tune the properties of perovskite oxides. In demanding high-power piezoelectric ceramic applications, acceptor doping is the most effective method to harden ceramics, but it inevitably degrades the ceramics' electromechanical properties. Herein, a poling method based on acceptor doping, namely, high-temperature poling, is implemented by applying an electric field above the Curie temperature for poling to achieve a balance of the properties of piezoelectric coefficient d₃₃ and mechanical quality factor Q_m. After high-temperature poling, the piezoelectric property of 0.6 mol % Mn-doped Pb_0.92Sr_0.08(Zr_0.533Ti_0.443Nb_0.024)O₃ is d₃₃ = 483 pC/N and Q_m = 448. Compared with the traditional poling, the piezoelectric coefficient d₃₃ of the high-temperature poling ceramics increased by approximately 40%, and Q_m also increased by nearly 18%. Therefore, high d₃₃ and Q_m were exhibited by our PZT piezoelectric ceramics. Rayleigh's law analysis, XRD, and transmission electron microscopy analysis show that, after high-temperature poling, the considerably increased d₃₃ is related to the large increase in the reversible domain wall motion in the intrinsic effect, while the slightly increased Q_m is related to the inhibited irreversible domain wall motion in the extrinsic effect. This study reports a method for high-temperature poling and provides insights into the design of high-power piezoelectric ceramics with high d₃₃ and Q_m.

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