Electronic correlations and partial gap in the bilayer nickelate La3Ni2O7

Abstract

The discovery of superconductivity with a critical temperature of about 80 K in La₃Ni₂O₇ single crystals under pressure has received enormous attention. La₃Ni₂O₇ is not superconducting under ambient pressure but exhibits a transition at T ^∗ ≃ 115 K. Understanding the electronic correlations and charge dynamics is an important step towards the origin of superconductivity and other instabilities. Here, our optical study shows that La₃Ni₂O₇ features strong electronic correlations which significantly reduce the electron's kinetic energy and place this system in the proximity of the Mott phase. The low-frequency optical conductivity reveals two Drude components arising from multiple bands at the Fermi level. The transition at T ^∗ removes the Drude component exhibiting non-Fermi liquid behavior, whereas the one with Fermi-liquid behavior is barely affected. These observations in combination with theoretical results suggest that the Fermi surface dominated by the Ni- <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub><mml:mrow><mml:mi>d</mml:mi></mml:mrow> <mml:mrow><mml:mn>3</mml:mn> <mml:msup><mml:mrow><mml:mi>z</mml:mi></mml:mrow> <mml:mrow><mml:mn>2</mml:mn></mml:mrow> </mml:msup> <mml:mo>-</mml:mo> <mml:msup><mml:mrow><mml:mi>r</mml:mi></mml:mrow> <mml:mrow><mml:mn>2</mml:mn></mml:mrow> </mml:msup> </mml:mrow> </mml:msub> </mml:math> orbital is removed due to the transition at T ^∗. Our experimental results provide pivotal information for understanding the transition at T ^∗ and superconductivity in La₃Ni₂O₇.