Electronic correlations and partial gap in the bilayer nickelate La3Ni2O7

Abstract

The discovery of superconductivity with a critical temperature of about 80 K in La3Ni2O7 single crystals under pressure has received enormous attention. La3Ni2O7 is not superconducting under ambient pressure but exhibits a transition at T ∗ ≃ 115 K. Understanding the electronic correlations and charge dynamics is an important step towards the origin of superconductivity and other instabilities. Here, our optical study shows that La3Ni2O7 features strong electronic correlations which significantly reduce the electron’s kinetic energy and place this system in the proximity of the Mott phase. The low-frequency optical conductivity reveals two Drude components arising from multiple bands at the Fermi level. The transition at T ∗ removes the Drude component exhibiting non-Fermi liquid behavior, whereas the one with Fermi-liquid behavior is barely affected. These observations in combination with theoretical results suggest that the Fermi surface dominated by the Ni- $${d}_{3{z}^{2}-{r}^{2}}$$ orbital is removed due to the transition at T ∗. Our experimental results provide pivotal information for understanding the transition at T ∗ and superconductivity in La3Ni2O7. The bilayer nickelate La3Ni2O7 was recently shown to be superconducting at high-pressure. Here the authors reveal strong electronic correlations and the opening of a partial gap, providing key information for understanding the nature of the density-wavelike transition at ambient pressure and superconductivity in this compound.