Optical Readout of Single-Molecule Magnets Magnetic Memories with Unpolarized Light

Abstract

Magnetic materials are widely used for many technologies in energy, health, transportation, computation, and data storage. For the latter, the readout of the magnetic state of a medium is crucial. Optical readout based on the magneto-optical Faraday effect was commercialized but soon abandoned because of the need for a complex circular polarization-sensitive readout. Combining chirality with magnetism can remove this obstacle, as chiral magnetic materials exhibit magneto-chiral dichroism, a differential absorption of unpolarized light dependent on their magnetic state. Molecular chemistry allows the rational introduction of chirality into single-molecule magnets (SMMs), ultimate nanoobjects capable of retaining magnetization. Here, we report the first experimental demonstration of optical detection of the magnetic state of an SMM using unpolarized light on a novel air-stable Dy-based chiral SMM featuring a strong single-ion magnetic anisotropy. These findings might represent a paradigm shift in the field of optical data readout technologies.