20:T40f,Na-S batteries are one type of molten salt battery and have been used to support stationary energy storage systems for several decades. Despite their successful applications based on long cycle lives and low cost of raw materials, Na-S cells require high temperatures above 300 °C for their operations, limiting their propagation into a wide range of applications. Herein, we demonstrate that Na-S cells with solid state active materials can perform well even at room temperature when sulfur-containing carbon composites generated from a simple thermal reaction were used as sulfur positive electrodes. Furthermore, this structure turned out to be robust during repeated (de)sodiation for ~500 cycles and enabled extraordinarily high rate performance when one-dimensional morphology is adopted using scalable electrospinning processes. The current study suggests that solid-state Na-S cells with appropriate atomic configurations of sulfur active materials could cover diverse battery applications where cost of raw materials is critical.21:T54f,Engineering novel electrode materials with unique architectures has a significant impact on tuning the structural/electrochemical properties for boosting the performance of secondary battery systems. Herein, starting from well-organized WS₂ nanorods, an ingenious design of a one-step method is proposed to prepare a bimetallic sulfide composite with a coaxial carbon coating layer, simply enabled by ZIF-8 introduction. Rich sulfur vacancies and WS₂ /ZnS heterojunctions can be simultaneously developed, that significantly improve ionic and electronic diffusion kinetics. In addition, a homogeneous carbon protective layer around the surface of the composite guarantees an outstanding structural stability, a reversible capacity of 170.8 mAh g^-1 after 5000 cycles at a high rate of 5 A g^-1 . A great potential in practical application is also exhibited, where a full cell based on the WS_2- _x /ZnS@C anode and the P2-Na_2/3 Ni_1/3 Mn_1/3 O₂ cathode can maintain a reversible capacity of 89.4 mAh g^-1 after 500 cycles at 1 A g^-1 . Moreover, the underlying electrochemical Na storage mechanisms are illustrated in detail by theoretical calculations, electrochemical kinetic analysis, and operando X-ray diffraction characterization.22:T450,Hybrid materials, integrating the merits of individual components, are ideal structures for efficient sodium storage. However, the construction of hybrid structures with decent physical/electrochemical properties is still challenging. Now, the elaborate design and synthesis of hierarchical nanoboxes composed of three-layered Cu₂ S@carbon@MoS₂ as anode materials for sodium-ion batteries is reported. Through a facile multistep template-engaged strategy, ultrathin MoS₂ nanosheets are grown on nitrogen-doped carbon-coated Cu₂ S nanoboxes to realize the Cu₂ S@carbon@MoS₂ configuration. The design shortens the diffusion path of electrons/Na⁺ ions, accommodates the volume change of electrodes during cycling, enhances the electric conductivity of the hybrids, and offers abundant active sites for sodium uptake. By virtue of these advantages, these three-layered Cu₂ S@carbon@MoS₂ hierarchical nanoboxes show excellent electrochemical properties in terms of decent rate capability and stable cycle life.23:T5c7,

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