Advanced Synthesis & Catalysis · 2024 · 20 citations · 30 references
Natural SciencesChemical EngineeringChemistryBiocatalysisCatalysisGreen ChemistryCarboxylic AcidsCatalytic MechanismsPhotocatalysisPhotochemical SynthesisPhotochemistryRedox CatalysisMild Reaction ConditionsPhotocatalytic OxidationPhotocatalytic SynthesisVisible-light Photocatalysis
Abstract The decarboxylative oxygenation of readily available carboxylic acids as well as the oxidation of alkenes and alkanes has been accomplished through visible light using g‐C 3 N 4 as a robust and recyclable catalyst. The scalable protocol furnishes an array of aldehydes and ketones under mild reaction conditions, requiring only molecular oxygen as an oxidant. Notably, no addition of stochiometric amounts of base is required, and furthermore, the reaction proceeds efficiently open to the air.
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Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
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Photoexcited nitroarenes for the oxidative cleavage of alkenes
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