Pre-doped cations in V ₂O ₅ for high-performance Zn-ion batteries

Abstract

Aqueous rechargeable zinc-ion batteries (ZIBs) have garnered considerable attention due to their safety, cost-effectiveness, and eco-friendliness. There is a growing interest in finding suitable cathode materials for ZIBs. Layered vanadium oxide has emerged as a promising option due to its ability to store zinc ions with high capacity. However, the advancement of high-performance ZIBs encounters obstacles such as sluggish diffusion of zinc ions resulting from the high energy barrier between V₂O₅ layers, degradation of electrode structure over time and consequently lower capacity than the theoretical value. In this study, we investigated the pre-doping of different cations (including , , and ) into V₂O₅ to enhance the overall charge storage performance. Our findings indicate that the presence of V⁴⁺ enhances the charge storage performance, while the introduction of &nbsp;into V₂O₅ (NH₄-V₂O₅) not only increases the interlayer distance (<em>d</em>₍₀₀₁₎ = 15.99 Å), but also significantly increases the V⁴⁺/V⁵⁺ redox couple (atomic concentration ratio increased from 0.14 to 1.08), resulting in the highest electrochemical performance. The NH₄-V₂O₅ cathode exhibited a high specific capacity (310.8 mAh·g^–1 at 100 mA·g^–1), improved cycling stability, and a significantly reduced charge transfer resistance (~ 17.9 Ω) compared to pristine V₂O₅ (112.5 mAh·g^–1 at 0.1 A·g^–1 and ~ 65.58 Ω charge transfer resistance). This study enhances our understanding and contributes to the development of high-capacity cathode materials, offering valuable insights for the design and optimization of cathode materials to enhance the electrochemical performance of ZIBs.