Influence of annealing temperature and laser irradiation on the structural, optical, and photoluminescence characteristics of Ni₂O₃/SnO₂ nanocomposites for perspective applications

Abstract

Abstract In this study, a new approach methodology is employed to modify the structural, optical, and photoluminescence properties of Ni 2 O 3 /SnO 2 (NO/TO) nanocomposites. The effects of temperature and laser irradiation on a specific system were analyzed and described using XRD, XPS, and TEM. The diffraction patterns indicate the presence of two distinct phases within the NO/TO system. The XPS results reveal a robust underlying interaction between Ni 2 O 3 and SnO 2 , exhibited by the observed shifts in the peak positions of Ni 2p, Sn 3d, and O 1 s. The TEM images demonstrate the formation of hexagonal and half-hexagonal forms with varying orientations, as well as the emergence of elongated tetragonal shapes, upon increasing the temperature to 900 °C. the notable enhancement in light absorption, with the absorption bands spanning a wide range in the UV–vis spectra, specifically from approximately 300 nm to around 800 nm in the near-infrared (NIR) region. The broad range of PL emission bands identified by this mixture of nanoparticles, expanding from the UV to the near and intermediate IR regions, demonstrated that NO/TO nanocpomposites are considerably defective. The NO/TO nanocomposites exhibit efficient multi-color band emissions at ambient conditions, rendering them promising contenders for deployment in optoelectronic nanodevices, including blue, yellow, and white band emission light-emitting diodes and NIR luminescence bioimaging.