ACS Nano · 2024 · 14 citations · 50 references
Natural SciencesMaterials EngineeringMaterials ScienceElectronic MaterialsPolymer ChemistryPolymer MaterialsElastomeric PolymersPolymer NetworksPolymer StabilityPolymer Thin FilmsSmart PolymersStrain EngineeringElastic ModuliHybrid Polymer CompositesInterpenetrating Polymer NetworksMechanical StabilityStrain IsolationStretchable ElectronicsStretchable MaterialsSubstrate Strain
Various strain isolation strategies that combine rigid and stretchable regions for stretchable electronics were recently proposed, but the vulnerability of inorganic materials to mechanical stress has emerged as a major impediment to their performance. We report a strain-isolation system that combines heteropolymers with different elastic moduli (i.e., hybrid stretchable polymers) and utilize it to construct a rugged island-bridge inorganic electronics system. Two types of prepolymers were simultaneously cross-linked to form an interpenetrating polymer network at the rigid-stretchable interface, resulting in a hybrid stretchable polymer that exhibited efficient strain isolation and mechanical stability. The system, including stretchable micro-LEDs and microheaters, demonstrated consistent operation under external strain, suggesting that the rugged island-bridge inorganic electronics mounted on a locally strain-isolated substrate offer a promising solution for replacing conventional stretchable electronics, enabling devices with a variety of form factors.
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Natural Sciences, Materials Engineering, Materials Science +14
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