Impact of <i>o</i>-aryl halogen effects on ethylene polymerization: steric <i>vs.</i> electronic effects

Abstract

-aryl halogens significantly impact the molecular weight of the polyethylene. The size of the halogen substituents primarily determines the molecular weight of the polyethylene. However, in terms of branching density, the steric and electronic effects of these substituents appear to counteract each other. In addition, the branched high molecular weight polyethylenes from the bromine and chlorine substituted nickel catalysts are excellent polyethylene thermoplastic elastomers with high strain at break values (688-2478%) and high strain recovery values (42-62%).