Concepedia

Nickel(0)-catalyzed ring-opening reaction of silacyclobutanes with 1,3-dienes to access allylsilane

Mengyuan Liu, Kexin Dong, Bing Xu, Zhan‐Ming Zhang, Zhong Wei, Junliang Zhang

Organic Chemistry Frontiers · 2024 · 12 citations · 34 references

DOI

Concepts

Abstract

Here we report a Ni-catalyzed highly regio- and stereoselective ring opening reaction of SCBs with 1,3-dienes for a straightforward and facile preparation of allylsilanes.

References

34

On the Bonding in Carbosilanes

Andreas Savin, Heinz‐Jürgen Flad, Jürgen Flad et al. · Angewandte Chemie International Edition in English · 1992 · 167 citations

, , +11

Divergent and Stereoselective Synthesis of β‐Silyl‐α‐Amino Acids through Palladium‐Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds

Yue‐Jin Liu, Yanhua Liu, Zhuo‐Zhuo Zhang et al. · Angewandte Chemie International Edition · 2016 · 149 citations

, , +8

Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes

Xing‐Ben Wang, Zhan‐Jiang Zheng, Jiale Xie et al. · Angewandte Chemie International Edition · 2019 · 147 citations

, , +16

Silane and Germane Molecular Electronics

Timothy A. Su, Haixing Li, Rebekka S. Klausen et al. · Accounts of Chemical Research · 2017 · 146 citations

, , +17

Synthesis of silacyclobutanes and their catalytic transformations enabled by transition-metal complexes

Qiu‐Chao Mu, Jing Chen, Chungu Xia et al. · Coordination Chemistry Reviews · 2018 · 143 citations

, , +12